Aerobic oxidative amination of unactivated alkenes catalyzed by palladium.
نویسندگان
چکیده
The first examples of palladium-catalyzed oxidative amination of unactivated alkyl olefins have been identified. To be successful, these reactions must be conducted under cocatalyst-free conditions that involve direct dioxygen-coupled turnover of the palladium catalyst. The oxidative amination products of norbornene and other cyclic alkenes implicate a cis-aminopalladation mechanism.
منابع مشابه
Palladium-catalyzed oxidative amination of alkenes: improved catalyst reoxidation enables the use of alkene as the limiting reagent.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 127 9 شماره
صفحات -
تاریخ انتشار 2005